Intermolecular Cope-type hydroamination of alkynes using hydrazines.
نویسندگان
چکیده
Metal-free, intermolecular hydroaminations are performed upon heating aryl acetylenes and MeNHNH(2) at 140 degrees C, with preferential formation of the linear, "anti-Markovnikov" hydrazones.
منابع مشابه
Rh(I) and Ir(I) catalysed intermolecular hydroamination with substituted hydrazines.
The catalysed intermolecular hydroamination of a series of terminal alkynes with substituted hydrazines was achieved using Rh(I) and Ir(I) complexes.
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عنوان ژورنال:
- Chemical communications
دوره 4 شماره
صفحات -
تاریخ انتشار 2008